Igor F. Perepichka

2019年05月08日 17:35  点击:[]


教育及工作经历

01/2019-present  Professor of Chemistry, Northwestern Polytechnical University, Institute of Flexible Electronics

07/2010 – 01/2019  Professor of Chemistry, Bangor University, School of Chemistry (renamed to School of Natural Sciences from Aug. 2018), Bangor, United Kingdom(Emeritus Professor from October 2018).

10/2007 – 06/2010  Reader in Chemistry, University of Central Lancashire, Centre for Materials Science, Preston, United Kingdom

01/2003 – 09/2007  Senior Research Associate, Durham University, Department of Chemistry, Durham, United KIngdom

09/2001 – 11/2002  Invited Professor, University of Angers, Laboratory of Molecular Engineering and Organic Materials, Angers, France

04/2001 – 07/2001  Visiting Scientist, CNRS (Centre National de la Recherché Scientifique), Angers, France

02/2000 – 10/2000  Visiting Scientist, CNRS (Centre National de la Recherché Scientifique), Angers, France

06/1999 – 08/1999  Visiting Scientist, CEA-Saclay (Comissariat á l’Énergie Atomique Saclay, Département d’Électronique et d’Instrumentation Nucléaire), Gif-sur-Yvette, France

09/1995 – 03/1997  Alexander von Humboldt Fellow, University of Würzburg, Institute of Organic Chemistry, Würzburg, Germany

06/1989 – 09/2007  Senior Research Scientist, National Academy of Sciences of Ukraine, Institute of Physical Organic and Coal Chemistry (IPOCC), Donetsk, Ukraine

02/1988 – 06/1989  Research Scientist, Ukrainian Academy of Sciences, IPOCC, Donetsk, Ukraine

04/1983 – 02/1988  Junior Researcher, Ukrainian Academy of Sciences, IPOCC, Donetsk, Ukraine

02/1983 – 04/1983  Senior Engineer, Ukrainian Academy of Sciences, IPOCC, Donetsk, Ukraine

11/1981 – 02/1983  Engineer, Ukrainian Academy of Sciences, IPOCC, Donetsk, Ukraine

1982 – 1986  PhD (Organic Chemistry) (02/1987). National Academy of Sciences of Ukraine, Institute of Physical Organic and Coal Chemistry, Donetsk, Ukraine

1976 – 1981  Diploma in Chemical Engineering, with Distinction (MSc equivalent, 06/1981). Donetsk Polytechnic Institute (currently: Donetsk Technical University), Donetsk, Ukraine

研究兴趣

Organic and polymer materials chemistry, organic/plastic electronics, photonics and nanoelectronics.

Design, synthesis and studies of molecular and polymeric materials for electronics, optoelectronics and photonics; nanomaterials; supramolecular architectures and self-organized systems. Understanding the structure–properties and structure–functions relationships.

•  conductive, semiconductive and photoconductive π-conjugated molecular and polymeric systems.

•  charge, electron and energy transfer in π-systems; photo- and electrochemistry of π-systems.

•  nano-sized conjugated macromolecular systems, supramolecular chemistry.

•  organic and polymer materials for light-emitting diodes (OLED) and electrochemical cells (LEC), photovoltaics (OPV), field-effect transistors (OFET), electrochromics (EC), non-linear optics (NLO), nanotechnologies, sensors/biosensors etc.

荣誉及奖励

2010  LCRI Chair (Low Carbon Research Institute)

2009  Fellow of The Royal Society of Chemistry, FRSC

2012, 2013, 2016  Santander Universities Research & Mobility Award.

2006, 2002, 1999  The Royal Society of Chemistry Journals Grant for International Authors, UK.

2002  NATO Expert Visitor Award (visit to Manchester University, UK).

2001  Chaire de Professeur Invité du PRIA (Pôle de Recherche et d'Innovation d’Angers), CCI (Chambrede Commerce et d'Industrie d'Angers), France.

1999  Senior Research Fellow (academic rank), Highest Attestation Commission of Ukraine.

2002, 2000, 1998, 1995 The Royal Society Exchange Visit Award, UK

1995  Alexander von Humboldt Fellowship, Germany.

1995, 1994, 1993  International Science Foundation, Travel Grant Awards.

科研基金

LCRI (Low Carbon Research Institute), ERDF funding, Grant WEFO-80366; 2010–2013; PI.

•  BIRAX (UK-Israel Collaborative Grant), “Functionalized Polyphenylselenophenes for Plastic Photovoltaic Cells Applications”, British Council, 2010–2011; PI.

•  125 BU Anniversary Scholarships (for PhD: S. Ghosh, 2010–2014; S. Kommanaboyina, 2011-2015).

•  A4B-KEP grant “Welsh Intelligent Polymer Processing Consortium For Functional Applications (WIP2C)”, ERDF, 2012-2013; co-PI.

•  Visiting Scholarships (for E. Klimareva: 2014; 2017).

•  Santander Universities Research & Mobility Awards, 2012, 2013, 2016.

•  RSC Journals Grant for International Authors, 2011.

•  PRIA – CCI (Pôle de Recherche et d'Innovation d’Angers – Chambre de Commerce et d'Industried'Angers), Plastic Photovoltaics Project. Invited Professorship, 2001–2002.

•  At National Academy of Science of Ukraine: Principal investigator (PI) and co-PI on over 20 academic and industry-oriented research programs and projects (1985–2000; direct funding through National Academy of Sciences of Ukraine as well as external funding by industry).

•  7 Research awards from the Royal Society (UK) and the Royal Society of Chemistry (1994–2002) for collaborative research visits to UK and Canada.

代表性论文

[1]J. Ning, W. Li, Y. Yin, X. Xing, M. Qi, T. Li, J. Cao, Y. He, I. F. Perepichka, H. Meng, Thieno[3,2-b]thiophene-based conjugated copolymers for solution-processable neutral black electrochromism, J. Mater. Chem. C, 2018, first published 31 October, 2018; DOI: 10.1039/c8py01208c.

[2] T. Darmanin, G. Godeau, F. Guittard, E. L. Klimareva, I. Schewtschenko, I. F. Perepichka, A templateless electropolymerization approach to porous hydrophobic nanostructures using 3,4-phenylenedioxythiophne monomers with electron-withdrawing groups.ChemNanoMat, 2018, 4, 656–662. DOI: 10.1002/cnma.201800068

[3]S. Ghosh, A. S. Alghunaim, M. Al-Mashhadani, M. P. Krompiec, M. Hallett, I. F. Perepichka, 4,5-Diazafluorene cooligomers as electron-deficient light-emitting materials and selective fluorescence sensors for mercury(II) cations. Journal of Materials Chemistry C, 2018, 6, 3762–3773. DOI: 10.10139/C7TC05051H

[4]M. P. Krompiec, S. N. Baxter, E. L. Klimareva, D. S. Yufit, D. G. Congrave, T. K. Britten, I. F. Perepichka,3,4-Phenylenedioxythiophenes (PheDOTs) functionalized with electron-withdrawing groups and their analogs for organic electronics.Journal of Materials Chemistry C, 2018, 6, 3743–3756. DOI: 10.1039/C7TC05227H

[5]S. Shao, J. Shi, I. Murtaza, P. Xu, Y. He, S. Ghosh, X. Zhu, I. F. Perepichka, H. Meng, Exploring the electrochromic properties of poly(thieno[3,2-b]thiophene)s decorated with electron-deficient side groups.Polymer Chemistry, 2017, 8, 769–784. DOI: 10.1039/C6PY01847E

[6]M. Zhu, W. Li, P. Xu, J. Shi, S. Shao, X. Zhu, Y. Guo, Y. He, Z. Hu, H. Yu, Y. Zhu, I. F. Perepichka, H. Meng, Molecular engineering tuning optoelectronic properties of thieno[3,2-b]thiophene-based electrochromic polymers.Science China Chemistry, 2017, 60, 63–76. DOI: 10.1007/s11426-016-0305-9

[7]A. Yu. Sosorev, O. D. Parashchuk, S. A. Zapunidi, G. S. Kashtanov, I. V. Golovnin, S. Kommanaboyina, I. F. Perepichka, D.Yu. Paraschuk, Threshold-like complexation of conjugated polymers with small molecule acceptors in solution within the neighbor-Effect Model.Physical Chemistry Chemical Physics, 2016, 18, 4684–4696. DOI: 10.1039/c5cp05266a

[8]S. A. Jabbar, I. F. Perepichka, S. A. Ahmed, Synthesis and characterization novel sulfonyl-containing fluorenes as materials for organic light-emitting diodes.Journal of the College of Basic Education, 2015, 21, No 89, 141–148. https://iasj.net/iasj?func=fulltext&aId=101694

[9]V. G. Pavelyev, O. D. Parashchuk, M. Krompiec, T. V. Orekhova, I. F. Perepichka, P. H. M. van Loosdrecht, D. Yu. Paraschuk,M. S. Pshenichnikov, Charge transfer dynamics in donor−acceptor complexes between a conjugated polymer and fluorene acceptors.Journal of Physical Chemistry C, 2014, 118, 30291−30301. DOI: 10.1021/jp510543c

[10]A. J. Blayney, I. F. Perepichka, F. Wudl, D. F. Perepichka, Advances and challenges in the synthesis of poly(p-phenylenevinylene)-based polymers.Israel Journal of Chemistry, 2014, 54, 674–688. (REVIEW) . DOI: 10.1002/ijch.201400067

[11]G. Tsiminis, N. A. Montgomery, A. L. Kanibolotsky, A. Ruseckas, I. F. Perepichka, P. J. Skabara, G. A. Turnbull, I. D. W.Samuel, Laser characteristics of a family of benzene-cored star-shaped oligofluorenes.Semiconductor Science and Technology, 2012, 27, p094005. DOI: 10.1088/0268-1242/27/9/094005

[12]E. Poverenov, Y. Sheynin, N. Zamoshchik, A. Patra, G. Leitus, I. F. Perepichka, M. Bendikov, Flat conjugated polymers combining a relatively low HOMO energy level and band gap: polyselenophenes versus polythiophenes.Journal of Materials Chemistry, 2012, 22, 14645–14655. DOI: 10.1039/c2jm31035j

[13]J. L. Zafra, J. Casado, I. I. Perepichka, I. F. Perepichka, M. R. Bryce, F. J. Ramírez, J. T. López Navarrete,π-Conjugation and charge polarization in fluorene–dibenzothiophene-S,S-dioxide co-oligomers by Raman spectroscopy and quantum chemistry.Journal of Chemical Physics, 2011, 134, 044520. DOI: 10.1063/1.352648711

[14]Y. Wang, G. Tsiminis, Y. Yang, A. Ruseskas, A. L. Kanibolotsky, I. F. Perepichka, P. J. Skabara, G. A. Turnbull, I. D. W.Samuel, Broadly tunable deep blue laser based on a star-shaped oligofluorene truxene.Synthetic Metals, 2010, 160, 1397–1400. DOI: 10.1016/j.synthmet.2010.04.016

[15]A. L. Kanibolotsky, I. F. Perepichka, P. J. Skabara, Star-shaped π π-conjugated oligomers and their applications in organic electronics and photonics.Chemical Society Reviews, 2010, 39, 2695–2728. (REVIEW). DOI: 10.1039/B918154G

[16]M. A. Kryuchkov, R. I. Zubatyuk, I. F. Perepichka, O. V. Shishkin, S. V. Tolkunov, A versatile synthesis of benzothieno-annelated 1,2-dihydropyridine and 1,2,3,4-tetrahydropyridine derivatives: the effect of the structure of benzothieno-annelated pyridinium salts on their reduction by sodium borohydride.Monatschefte Chemie, 2010, 141, 35–53. DOI: 10.1007/s00706-009-0222-7

代表性专著

[1] S. Xun, D. F. Perepichka, I. F. Perepichka, H. Meng, F. Wudl, Light-Emitting Polymers. – Chapter 2, in Book: Organic Light-Emitting Materials and Devices, Second Edition, Z. R. Li (Ed.), CRC Press, Boca Raton,FL, 2 nd Edition, 2015, pp. 41–308.

[2] D. F. Perepichka, I. F. Perepichka, F. Wudl, Special Issue on Organic Electronics: In Memory of Prof. Michael Bendikov(1971–2013).– Israel Journal of Chemistry, 2014, 54, 426–228 (Editorial). DOI: 10.1002/ijch.201410008

[3] V. G. Pavelyev, O. D. Parashchuk, T. V. Orekhova, I. F. Perepichka, D. Yu. Paraschuk, P. H. M. van Loosdrecht, M. S.Pshenichnikov, Acceptor Energy Offset Manages Ultrafast Recombination Dynamics in Donor-Acceptor Mixtures.– Book Series: EPJ Web of Conferences, 2013, 41, 05036. DOI: 10.1051/epjconf20134105036

[4] J. L. Zafra, I. I. Perepichka, I. F. Perepichka, M. R. Bryce, F. J. Ramírez, J. Casado, J. T. López Navarrete, Raman spectra and quantum chemistry calculations of fluorene–dibenzothiophene-S,S-dioxide oligomers.– AIP Conference Proceedings, 2010, 1267, 683-684. DOI: 10.1063/1.3482749

[5] I. F. Perepichka, D. F. Perepichka (Eds),– Book: Handbook of Thiophene-Based Materials: Applications in Organic Electronics and Photonics. Two-Volumes

Set (Vol. 1: Synthesis and Theory, Vol. 2: Properties and Applications), Wiley, 2009, 910 pp.,ISBN: 978-0-470-05732-2. http://eu.wiley.com/WileyCDA/WileyTitle/productCd-0470057327.html

[6] I. F. Perepichka, D. F. Perepichka, H. Meng, Thiophene-Based Materials for Electroluminescent Applications.Chapter in Book: Handbook of Thiophene-Based Materials: Applications in Organic Electronics and Photonics, Volume 2:Properties and Applications, I. F. Perepichka and D. F. Perepichka (Eds.), Wiley, 2009, Chapter 19, pp. 695–756.

[7] D. F. Perepichka, I. F. Perepichka, H. Meng, F. Wudl, Light-Emitting Polymers.– Chapter in Book: Organic Light-Emitting Materials and Devices, Z. R. Li and H. Meng, Eds., CRC Press, Boca Raton, FL,2006, Chapter 2, pp. 45–293.17

[8] D. D.Mysyk, I. F.Perepichka, N. I.Sokolov, L. I. Kostenko, Fluoroalkyl esters of 9-substituted polynitrofluorene-4-carboxylic acids: synthesis, complexation with anthracene and sensitization of photoconductivity of poly-N-epoxypropyl carbazole.– In Collected Volume: Transactions of DonNTU. Section: Chemistry and Chemical Engineering. Donetsk National State University Publisher, Donetsk, 2001, Issue 33, p.22–36.

[9] I. F. Perepichka, Electron acceptors of the fluorene series in photonics and electronics: recent achievements and perspectives.– In: “Multiphoton and Light Driven Multielectron Processes in Organics: Materials, Phenomena, Applications”, NATO Science Series: 3. High Technology – Vol. 79, F. Kajzar and M. V. Agranovich (Eds.), Kluwer Academic Publishers, Dordrecht, 2000,pp. 371–386.

[10] M. R. Bryce, A. J. Moore, A. S. Batsanov, J. A. K. Howard, N. Robertson, I. F. Perepichka, A new range of functionalised tetrathiafulvalenes and their cation radical salts: synthetic and solid state studies– In: “Supramolecular Engineering of Synthetic Metallic Materials: Conductors and Magnets.” NATO ASI Series, Vol. 518, J.Veciana, C. Rovira and D. B. Amabilino (Eds.), Kluwer Academic Publishers, Dordrecht, 1999, pp. 437–449.

[11] D. F. Perepichka, I. F. Perepichka, M. R. Bryce, A. F. Popov, A. Chesney, A. J. Moore, Correlation analysis of intramolecular charge transfer in nitrosubstituted fluorenes containing 1,3-dithioles and metallocenes as donor moieties. An approach to advanced optical materials.– In Collected Volume: Structures of Organic Compounds and Reaction Mechanisms, Inst. Phys. Org. & Coal Chem., Donetsk,1998, p. 94–100.

[12] N. I. Sokolov, Y. M. Barabash, L. V. Poperenko, I. F. Perepichka, D. D. Mysyk, L. I. Kostenko, Optimization of photothermoplastic materials for rainbow hologram recording.– SPIE Proceedings, 1997, Vol. 3055, 170–179.

[13] I. F. Perepichka, A. F. Popov, Nucleophilic addition of amines to the activated ethylene bond in non-aqueous media.– In Collected Volume: "Atualidades de Físico-Química Orgânica", E. Humeres (Ed.), Florianópolis, Brazil, 1995, pp. 471–-490.

[14] I. F. Perepichka, D. D. Mysyk, N. I. Sokolov, Photoconductivity of carbazole-containing polymers sensitized by electron acceptors.– Chapter in Book: Current Trends in Polymer Photochemistry, N. S. Allen, M. Edge, I. R. Bellobono and E. Selli, Ellis Horwood(Eds.), New York-London, 1995, pp. 318–327.

[15] A. F. Popov, I. F. Perepichka, V. V. Kravchenko, Nucleophilic addition of amines to the activated ethylene bonds. Part 5.Effects of specific solvatation on the rate of interaction between p-metoxyphenyl vinyl ketone and diethylamine.– Deposited Article UkrINTEI, 1992, No 647-UK92, 16 p. (in Russian).

[16] L. A. Perelman, S. A. Grebenyuk, L. I. Kostenko, N. I. Sokolov, I. F. Perepichka, Modified poly-N-epoxypropylcarbazoles and photosensitive layers on their base.– Deposited Article VINITI, 1990, No 2572-B90, 15 p. (in Russian).

[17] I.F.Perepichka, A.F.Popov, L.I.Kostenko, T.V.Art'omova, J.Kovač, Kinetics and mechanism of the interaction between trans-2-(β β-nitrovinyl)furan and amines. II. Role of tertiary amines.– In Book: Studies in Organic Chemistry. 35. Chemistry of Heterocyclic Compounds, Eds. J. Kovač and P. Zalupsky, Elsevier,Amsterdam-Oxford-NY-Tokyo, 1988, p.462–465.

[18]I. F. Perepichka, A. F. Popov, L. I. Kostenko, T. V. Art'omova, J. Kovač, Kinetics and mechanism of the interaction between trans-2-(β β-nitrovinyl)furan and amines. I.– In Book: Studies in Organic Chemistry. 35. Chemistry of Heterocyclic Compounds, Eds. J. Kovač and P. Zalupsky, Elsevier,Amsterdam-Oxford-NY-Tokyo, 1988, p.457–461.

[19] L. I. Kostenko, L. A. Perelman, V. V. Kravchenko, A. A. Miroshnichenko, I. F. Perepichka, A. F. Popov, Intramolecular catalysis in aminolysis reactions of oxiranes.– In Book: Studies in Organic Chemistry. 35. Chemistry of Heterocyclic Compounds, Eds. J. Kovač and P. Zalupsky., Elsevier,Amsterdam-Oxford-NY-Tokyo, 1988, p.352–355.

[20] D. D. Mysyk, I. F. Perepichka, N. M. Sivchenkova, L. I. Kostenko, I. S. Pototskii, Sensitizers of the fluorene series for electrophotographic layers. Synthesis of 2,4,7-trinitrofluorenone, amides of polynitrofluorenon-4-carboxylic acids and their condensation with malononitrile.– In Book: Electronics of Organic Materials, Moscow, Nauka, 1985, p. 351–353 (in Russian).

[21] I. F. Perepichka, D. D. Mysyk, Identification of electron acceptors of fluorene series by thin-layer chromatography.– Deposited Article ONIITEKHIM, 1982, No 101хп-Д82, 14 p.; summary in: Reference Bulletin VINITI "Deposited Articles",1982, No 4, 93 (in Russian).


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